Self‐Assembly of Chiral Nano‐bowl from Chiral Pd‐complex Building Corners and 4, 7‐Phenanthroline Linkers. Issue 1 (4th April 2014)

• Record Type: Journal Article
• Authors: Yu, Lina; Jiang, Xuanfeng; Yu, Shuyan
• Is Part Of: Chinese journal of chemistry. Volume 33:Issue 1(2015:Jan.)
• Page Start: 152
• Page End: 155
• Publication Date: 2014-04-04
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cjoc.201400085
• Languages: English
• ISSNs: 1001-604X

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A chiral [M₃<bold>L</bold>₃]⁶⁺‐type nanobowl reported here was self‐assembled from <italic>cis</italic>‐protected mono‐palladium complex [(RRdiph)Pd](NO₃)₂ (where RRdiph= (1<italic>R</italic>, 2<italic>R</italic>)‐(+)‐1, 2‐diphenylethylenediamine) as chiral corners and 4, 7‐phenanthroline ligand (<bold>L</bold>) as linkers in aqueous media. The hydrophobic cavity‐containing metallo‐macrocycle [Pd₃<bold>L</bold>₃]⁶⁺·6NO₃ (<bold>1</bold>) with a<italic> syn, syn, syn</italic> orientation has been characterized by ¹H NMR spectroscopy, elemental analysis, CD spectra and X‐ray diffraction determination.</p> </abstract>