One‐pot Synthesis of CdS Nanocrystals Hybridized with Single‐Layer Transition‐Metal Dichalcogenide Nanosheets for Efficient Photocatalytic Hydrogen Evolution1. (3rd December 2014)

• Record Type: Journal Article
• Authors: Chen, Junze; Wu, Xue‐Jun; Yin, Lisha; Li, Bing; Hong, Xun; Fan, Zhanxi; Chen, Bo; Xue, Can; Zhang, Hua
• Is Part Of: Angewandte Chemie. Volume 127:Number 4(2015)
• Page Start: 1226
• Page End: 1230
• Publication Date: 2014-12-03
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201410172
• Languages: English
• ISSNs: 0044-8249

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Exploration of low‐cost and earth‐abundant photocatalysts for highly efficient solar photocatalytic water splitting is of great importance. Although transition‐metal dichalcogenides (TMDs) showed outstanding performance as co‐catalysts for the hydrogen evolution reaction (HER), designing TMD‐hybridized photocatalysts with abundant active sites for the HER still remains challenge. Here, a facile one‐pot wet‐chemical method is developed to prepare <italic>M</italic>S₂–CdS (<italic>M</italic>=W or Mo) nanohybrids. Surprisedly, in the obtained nanohybrids, single‐layer <italic>M</italic>S₂ nanosheets with lateral size of 4–10 nm selectively grow on the Cd‐rich (0001) surface of wurtzite CdS nanocrystals. These <italic>M</italic>S₂–CdS nanohybrids possess a large number of edge sites in the <italic>M</italic>S₂ layers, which are active sites for the HER. The photocatalytic performances of WS₂–CdS and MoS₂–CdS nanohybrids towards the HER under visible light irradiation (&gt;420 nm) are about 16 and 12 times that of pure CdS, respectively. Importantly, the <italic>M</italic>S₂–CdS nanohybrids showed enhanced stability after a long‐time test (16 h), and 70 % of catalytic activity still remained.</p> </abstract>