<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Application of an iridium photoredox catalyst IPC in combination with a nickel catalyst effects the cross‐coupling of potassium alkoxyalkyl‐ and benzyltrifluoroborates with various aryl bromides under exceptionally mild conditions (visible light, ambient temperature, no strong base).</p> </abstract>