An Alternative Mechanism for the Cobalt‐Catalyzed Isomerization of Terminal Alkenes to (Z)‐2‐Alkenes1. Issue 3 (27th November 2014)
- Record Type:
- Journal Article
- Title:
- An Alternative Mechanism for the Cobalt‐Catalyzed Isomerization of Terminal Alkenes to (Z)‐2‐Alkenes1. Issue 3 (27th November 2014)
- Main Title:
- An Alternative Mechanism for the Cobalt‐Catalyzed Isomerization of Terminal Alkenes to (Z)‐2‐Alkenes1
- Authors:
- Schmidt, Anastasia
Nödling, Alexander R.
Hilt, Gerhard - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The cobalt‐catalyzed selective isomerization of terminal alkenes to the thermodynamically less‐stable (Z)‐2‐alkenes at ambient temperatures takes place by a new mechanism involving the transfer of a hydrogen atom from a Ph<sub>2</sub>PH ligand to the starting material and the formation of a phosphenium complex, which recycles the Ph<sub>2</sub>PH complex through a 1, 2‐H shift.</p> </abstract>
- Is Part Of:
- Angewandte Chemie international edition. Volume 54:Issue 3(2015)
- Journal:
- Angewandte Chemie international edition
- Issue:
- Volume 54:Issue 3(2015)
- Issue Display:
- Volume 54, Issue 3 (2015)
- Year:
- 2015
- Volume:
- 54
- Issue:
- 3
- Issue Sort Value:
- 2015-0054-0003-0000
- Page Start:
- 801
- Page End:
- 804
- Publication Date:
- 2014-11-27
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3773 ↗
http://www.interscience.wiley.com/jpages/1433-7851 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/anie.201409902 ↗
- Languages:
- English
- ISSNs:
- 1433-7851
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3772.xml