Direct ortho‐Acylation of Azoxybenzenes with Aldehydes via Palladium‐Catalyzed Regioselective CH Bond Activation. Issue 1 (4th December 2014)

• Record Type: Journal Article
• Authors: Yi, Meiling; Cui, Xiuling; Zhu, Chongwei; Pi, Chao; Zhu, Weimin; Wu, Yangjie
• Is Part Of: Asian journal of organic chemistry. Volume 4:Issue 1(2015:Jan.)
• Page Start: 38
• Page End: 41
• Publication Date: 2014-12-04
• Subjects: Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; 547.005
• DOI: 10.1002/ajoc.201402251
• Languages: English
• ISSNs: 2193-5807

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A highly efficient and convenient palladium catalyzed the <italic>ortho</italic>‐acylation of azoxybenzenes has been developed. Easily available aldehydes were used as a cheap and ideal aroyl sources. This method provides a practical and direct pathway to synthesize 2‐acylated azoxybenzenes in chemo‐ and regioselective manners via palladium‐catalyzed CH bond activation. Various substituents on both coupling partners are tolerated well.</p> </abstract>