Double Columnar Structure with a Nanogradient Composite for Increased Oxygen Diffusivity and Reduction Activity. Issue 17 (17th July 2014)

• Record Type: Journal Article
• Authors: Ju, Young‐Wan; Hyodo, Junji; Inoishi, Atsushi; Ida, Shintaro; Tohei, Tetsuya; So, Yeong‐Gi; Ikuhara, Yuichi; Ishihara, Tatsumi
• Is Part Of: Advanced energy materials. Volume 4:Issue 17(2014)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2014-07-17
• Subjects: Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201400783
• Languages: English
• ISSNs: 1614-6832

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The cathodic performances that can be achieved in solid oxide fuel cells (SOFCs), particularly in terms of oxygen diffusion, need to be improved so that high power densities can be produced at intermediate temperatures. Here, to improve the cathodic performance, a double columnar functional interlayer (DCFL) consisting of Sm<sub>0.2</sub>Ce<sub>0.8</sub>O<sub>2−δ</sub> (SDC) and Sm<sub>0.5</sub>Sr<sub>0.5</sub>CoO<sub>3−<italic>δ</italic></sub> (SSC) is fabricated between a La<sub>0.9</sub>Sr<sub>0.1</sub>Ga<sub>0.8</sub>Mg<sub>0.2</sub>O<sub>3−<italic>δ</italic></sub> electrolyte film and a SSC cathode film with pulsed laser deposition. The DCFL has a rough surface morphology consisting of nanosized grains (with diameters less than 5 nm), and it is formed of small columns that grow at an angle of ca. 45° from the substrate. Inserting the DCFL causes the electrical conductivity of the cathode to increase significantly, and the power density obtained by using it in a metal‐supported SOFC is increased. Atomic resolution scanning transmission electron microscopy (TEM) images and density functional theory calculations confirm that the samarium atoms in the SDC columns and cobalt atoms in the SSC columns are located at the interfaces between SDC and SSC columns. Therefore, it is possible a SmCoO<sub>3−<italic>δ</italic></sub> nanogradient is formed, which may cause lattice distortions. The <sup>18</sup>O<sub>2</sub> concentration is actually much higher in the DCFL than in either of SSC or SDC films.</p> </abstract>