Diastereoselective Synthesis of Vicinally Bis(trifluoromethylated) Alkylboron Compounds through Successive Insertions of 2, 2, 2‐Trifluorodiazoethane1. (24th October 2014)
- Record Type:
- Journal Article
- Title:
- Diastereoselective Synthesis of Vicinally Bis(trifluoromethylated) Alkylboron Compounds through Successive Insertions of 2, 2, 2‐Trifluorodiazoethane1. (24th October 2014)
- Main Title:
- Diastereoselective Synthesis of Vicinally Bis(trifluoromethylated) Alkylboron Compounds through Successive Insertions of 2, 2, 2‐Trifluorodiazoethane1
- Authors:
- Molander, Gary A.
Ryu, DaWeon - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The usefulness of embedded CF<sub>3</sub> substituents within organic substructures necessitates the development of diverse methods for incorporating this functional group. A recently reported route to α‐trifluoromethylated alkylboron compounds by an α‐transfer mechanism has now been extended to the synthesis of unprecedented, vicinally ditrifluoromethylated alkylboron compounds in a diastereoselective fashion. The utility of these products is highlighted by conversion of the CB bond into other functional groups.</p> </abstract>
- Is Part Of:
- Angewandte Chemie. Volume 126:Number 51(2014)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 126:Number 51(2014)
- Issue Display:
- Volume 126, Issue 51 (2014)
- Year:
- 2014
- Volume:
- 126
- Issue:
- 51
- Issue Sort Value:
- 2014-0126-0051-0000
- Page Start:
- 14405
- Page End:
- 14409
- Publication Date:
- 2014-10-24
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201408191 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 4149.xml