Chirality Sensing and Size Discrimination of Anions by Macrotricyclic Cyclen–Disodium Complexes1. Issue 6 (17th September 2014)
- Record Type:
- Journal Article
- Title:
- Chirality Sensing and Size Discrimination of Anions by Macrotricyclic Cyclen–Disodium Complexes1. Issue 6 (17th September 2014)
- Main Title:
- Chirality Sensing and Size Discrimination of Anions by Macrotricyclic Cyclen–Disodium Complexes1
- Authors:
- Ito, Hiroshi
Shinoda, Satoshi - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Two macrotricyclic ligands composed of two face‐to‐face octadentate metal chelates were synthesized. These cage‐shaped disodium complexes had special recognition ability for various counter anions. Specific chiral dicarboxylates bound to the complexes within the cavity and exhibited chirality induction properties. For instance, <italic>N</italic>‐Boc‐Asp dianion strongly induced circular dichroism (CD) signals, but <italic>N</italic>‐Boc‐Glu dianion, which is one carbon longer, did not.</p> </abstract>
- Is Part Of:
- ChemistryOpen. Volume 3:Issue 6(2014:Dec.)
- Journal:
- ChemistryOpen
- Issue:
- Volume 3:Issue 6(2014:Dec.)
- Issue Display:
- Volume 3, Issue 6 (2014)
- Year:
- 2014
- Volume:
- 3
- Issue:
- 6
- Issue Sort Value:
- 2014-0003-0006-0000
- Page Start:
- 238
- Page End:
- 241
- Publication Date:
- 2014-09-17
- Subjects:
- Chemistry -- Periodicals
540
540.5 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)2191-1363 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/open.201402049 ↗
- Languages:
- English
- ISSNs:
- 2191-1363
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3145.xml