Cover Picture: Platinum Complexes of a Borane‐Appended Analogue of 1, 1′‐Bis(diphenylphosphino)ferrocene: Flexible Borane Coordination Modes and in situ Vinylborane Formation (Chem. Eur. J. 51/2014). Issue 51 (15th December 2014)

• Record Type: Journal Article
• Authors: Cowie, Bradley E.; Emslie, David J. H.
• Is Part Of: Chemistry. Volume 20:Issue 51(2014)
• Page Start: 16781
• Page End: 16781
• Publication Date: 2014-12-15
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201490210
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>An arylborane‐appended analogue</bold> of the catalytically important dppf ligand, FcPPB, was prepared and is represented by the industrial robot in the image. FcPPB provided access to platinum complexes featuring η³<italic>BCC</italic>‐, η²<italic>BC</italic>‐, η¹<italic>B</italic>‐ and Pt–H–B coordination modes, and reaction of the η³<italic>BCC</italic>‐coordinated complex with PhC₂H transformed the arylborane into an η³<italic>BCC</italic>‐coordinated vinylborane. For details, see the Full Paper by B. E. Cowie and D. J. H. Emslie on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">pp. 16899 ff.</ext-link> (FcBBB=1′‐{(<italic>ortho</italic>‐diphenylborylphenyl)‐<italic>tert</italic>‐butylphosphino}‐1‐diphenylphosphinoferrocene)<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgh2qsv5494" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>