Breathing Pores on Command: Redox‐Responsive Spongy Membranes from Poly(ferrocenylsilane)s1. Issue 50 (24th October 2014)

• Record Type: Journal Article
• Authors: Zhang, Kaihuan; Feng, Xueling; Sui, Xiaofeng; Hempenius, Mark A.; Vancso, G. Julius
• Is Part Of: Angewandte Chemie international edition. Volume 53:Issue 50(2014)
• Page Start: 13789
• Page End: 13793
• Publication Date: 2014-10-24
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201408010
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Redox‐responsive porous membranes can be readily formed by electrostatic complexation between redox active poly(ferrocenylsilane) PFS‐based poly(ionic liquid)s and organic acids. Redox‐induced changes on this membrane demonstrated reversible switching between more open and more closed porous structures. By taking advantage of the structure changes in the oxidized and reduced states, the porous membrane exhibits reversible permeability control and shows great potential in gated filtration, catalysis, and controlled release.</p> </abstract>