A 3‐Pyridyl‐5, 15‐Diazaporphyrin Nickel(II) Complex as a Bidentate Metalloligand for Transition Metals1. (22nd October 2014)
- Record Type:
- Journal Article
- Title:
- A 3‐Pyridyl‐5, 15‐Diazaporphyrin Nickel(II) Complex as a Bidentate Metalloligand for Transition Metals1. (22nd October 2014)
- Main Title:
- A 3‐Pyridyl‐5, 15‐Diazaporphyrin Nickel(II) Complex as a Bidentate Metalloligand for Transition Metals1
- Authors:
- Yamaji, Ayaka
Shin, Ji‐Young
Miyake, Yoshihiro
Shinokubo, Hiroshi - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>3‐Pyridyl‐5, 15‐diazaporphyrin nickel(II) serves as a bidentate metalloligand for platinum(II), ruthenium(II), and rhenium(I) metal centers. Single‐crystal X‐ray diffraction analysis of these metal complexes unambiguously reveals the presence of a dative bond between the outer metal center and the <italic>meso</italic>‐nitrogen atom. The UV/Vis absorption spectra of the complexes show substantially red‐shifted bands which are perturbed by outer‐metal coordination. This is due to the contribution of metal‐to‐ligand charge transfer interactions.</p> </abstract>
- Is Part Of:
- Angewandte Chemie. Volume 126:Number 50(2014)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 126:Number 50(2014)
- Issue Display:
- Volume 126, Issue 50 (2014)
- Year:
- 2014
- Volume:
- 126
- Issue:
- 50
- Issue Sort Value:
- 2014-0126-0050-0000
- Page Start:
- 14144
- Page End:
- 14147
- Publication Date:
- 2014-10-22
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201408852 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 4328.xml