The development of uranium isotopic ratio analysis for uranium‐bearing particles by using oxygen flooding technique with SIMS. (November 2014)

• Record Type: Journal Article
• Authors: Shen, Yan; Zhang, Yan; Zhao, Yonggang; Wang, Tongxin; Wang, Fan; Lee, Yeonhee; Moon, DaeWon; Kang, Hee Jae; Kim, Kyung Joong; Lee, Tae Geol; Lee, Jae Cheol; Yi, Keewook; Hong, Tae Eun
• Is Part Of: Surface and interface analysis. Volume 46:Number 1(2014:Jan.)
• Page Start: 326
• Page End: 329
• Publication Date: 2014-11
• Subjects: Surfaces (Physics) -- Periodicals; Surface chemistry -- Periodicals; Thin films -- Periodicals; 541.33
• DOI: 10.1002/sia.5673
• Languages: English
• ISSNs: 0142-2421

Abstract

<abstract abstract-type="main"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The isotopic ratio of uranium‐bearing particles could be used to detect undeclared nuclear activities. How to strengthen the analyzing ability of secondary ion mass spectrometry (SIMS) was important to get certain information. For this purpose, the oxygen flooding technique was studied to enhance the ability of measuring isotopic ratio in uranium particles. The influence of oxygen flooding on the sensitivity of U<sup>+</sup>, UO<sup>+</sup> and UO<sub>2</sub><sup>+</sup> was checked by using uranium metal and uranium particle (CRM U200) samples. The major and minor isotopic ratios of uranium bearing particles were measured by U<sup>+</sup>, UO<sup>+</sup> and UO<sub>2</sub><sup>+</sup>. The result shows that the use of oxygen flooding technique has no effect on the sensitivity of U<sup>+</sup> and the isotopic ratio <sup>234</sup>U/<sup>238</sup>U and <sup>235</sup>U/<sup>238</sup>U. However, the intensity of UO<sup>+</sup> and UO<sub>2</sub><sup>+</sup> increased several times with the oxygen flooding. Besides, the accuracy and precision of major isotopic ratio measured by uranium–oxygen ions were better than that measured by U<sup>+</sup>. For the minor isotopic ratio (<sup>234</sup>U/<sup>238</sup>U), it cannot be measured by uranium–oxygen ions because of the interference of polyatomic ions on carbon mat. After changing sample mat, for example, silicon mat, it can be measured by UO<sup>+</sup> and get better results with oxygen flooding technique. Copyright © 2014 John Wiley & Sons, Ltd.</p> </abstract>