Coordination Architectures of Manganese Complexes based on the Liagnd 3‐Pytza or Mixed Ligands [3‐Pytza = 5‐(3‐Pyridyl)tetrazole‐2‐acetato]. Issue 12 (30th September 2014)

• Record Type: Journal Article
• Authors: Zou, Jian Hua; Tian, He; Wang, Zhong; Li, Fu Song; Zhang, Fei Fei; Zhao, Li Yang; Zhang, Ping; Zhu, Da Liang; Yang, Gao Wen; Li, Qiao Yun
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 640:Issue 12/13(2014)
• Page Start: 2566
• Page End: 2570
• Publication Date: 2014-09-30
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201400252
• Languages: English
• ISSNs: 0044-2313

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Reactions of K3‐pytza [K3‐pytza = 5‐(3‐pyridyl) tetrazole‐2‐acetato potassium salt] with MnCl₂<bold>·</bold>4H₂O and 4, 4′‐bipy or mixed ligands with 4, 4′‐bipy (4, 4′bipy = 4, 4′‐bipyridine), produced two new coordination compounds, [Mn(3‐pytza)₂(H₂O)₂]<bold>·</bold>2H₂O (<bold>1</bold>) and [Mn(3‐pytza)₂(4, 4′‐bipy)] (<bold>2</bold>). The two compounds were characterized by elemental analysis, IR spectroscopy and single‐crystal X‐ray diffraction. The X‐ray diffraction analysis reveals that compound <bold>1</bold> displays a 1D polymeric chain structure, whereas compound <bold>2</bold> shows a 2D layer network. The two polymers are self‐assembled to form 3D supramolecular networks by hydrogen bonding interactions. Furthermore, the luminescence of <bold>1</bold> and <bold>2</bold> in the solid state at room temperature were also investigated.</p> </abstract>