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Access to trans‐3, 4‐Dihydroxy‐2‐alkylpyrrolidines and Piperidines by Use of Stereodefined Cyclic N, O‐Acetals as a Diversity‐Generating Element. Issue 49 (13th October 2014)
Record Type:
Journal Article
Title:
Access to trans‐3, 4‐Dihydroxy‐2‐alkylpyrrolidines and Piperidines by Use of Stereodefined Cyclic N, O‐Acetals as a Diversity‐Generating Element. Issue 49 (13th October 2014)
Main Title:
Access to trans‐3, 4‐Dihydroxy‐2‐alkylpyrrolidines and Piperidines by Use of Stereodefined Cyclic N, O‐Acetals as a Diversity‐Generating Element
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A highly efficient and stereoselective synthetic pathway towards <italic>trans</italic>‐3, 4‐dihydroxy‐2‐alkylpyrrolidines and piperidines is described. The nature of the protecting groups on the hydroxyl moieties played a crucial role on the <italic>trans</italic> selectivity. By using this method, a concise total synthesis of (−)‐2‐epilentiginosine has been achieved.</p> </abstract>