Exchange‐Coupled fct‐FePd/α‐Fe Nanocomposite Magnets Converted from Pd/Fe3O4 Core/Shell Nanoparticles. Issue 46 (26th September 2014)

• Record Type: Journal Article
• Authors: Liu, Fei; Dong, Yunhe; Yang, Wenlong; Yu, Jing; Xu, Zhichuan; Hou, Yanglong
• Is Part Of: Chemistry. Volume 20:Issue 46(2014)
• Page Start: 15197
• Page End: 15202
• Publication Date: 2014-09-26
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201403787
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>We report the controlled synthesis of exchange‐coupled face‐centered tetragonal (fct) FePd/α‐Fe nanocomposite magnets with variable Fe concentration. The composite was converted from Pd/Fe₃O₄ core/shell nanoparticles through a high‐temperature annealing process in a reducing atmosphere. The shell thickness of core/shell Pd/Fe₃O₄ nanoparticles could be readily tuned, and subsequently the concentration of Fe in nanocomposite magnets was controlled. Upon annealing reduction, the hard magnetic fct‐FePd phase was formed by the interdiffusion between reduced α‐Fe and face‐centered cubic (fcc) Pd, whereas the excessive α‐Fe remained around the fct‐FePd grains, realizing exchange coupling between the soft magnetic α‐Fe and hard magnetic fct‐FePd phases. Magnetic measurements showed variation in the magnetic properties of the nanocomposite magnets with different compositions, indicating distinct exchange coupling at the interfaces. The coercivity of the exchange‐coupled nanocomposites could be tuned from 0.7 to 2.8 kOe and the saturation magnetization could be controlled from 93 to 160 emu g⁻¹. This work provides a bottom‐up approach using exchange‐coupled nanocomposites for engineering advanced permanent magnets with controllable magnetic properties.</p> </abstract>