A Facile Asymmetric Approach to the Multicyclic Core Structure of Mangicol A. Issue 49 (10th October 2014)
- Record Type:
- Journal Article
- Title:
- A Facile Asymmetric Approach to the Multicyclic Core Structure of Mangicol A. Issue 49 (10th October 2014)
- Main Title:
- A Facile Asymmetric Approach to the Multicyclic Core Structure of Mangicol A
- Authors:
- Ying, Jun
Pu, Lin - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Chiral propargylic ether‐based triene–ynes are synthesized with high enantiomeric purity by employing an asymmetric enyne addition to aldehydes catalyzed by 1, 1′‐bi‐2‐naphthol in combination with ZnEt<sub>2</sub>, Ti(O<italic>i</italic>Pr)<sub>4</sub> and dicyclohexylamine at room temperature. These substrates are found to undergo a one‐pot domino Pauson–Khand and Diels–Alder cycloaddition catalyzed by [RhCl(CO)<sub>2</sub>]<sub>2</sub> under CO to generate a series of multicyclic products with high chemoselectivity and stereoselectivity. These products contain the multicyclic core structure of mangicol A which could facilitate the synthesis and study of this class of natural products.</p> </abstract>
- Is Part Of:
- Chemistry. Volume 20:Issue 49(2014)
- Journal:
- Chemistry
- Issue:
- Volume 20:Issue 49(2014)
- Issue Display:
- Volume 20, Issue 49 (2014)
- Year:
- 2014
- Volume:
- 20
- Issue:
- 49
- Issue Sort Value:
- 2014-0020-0049-0000
- Page Start:
- 16301
- Page End:
- 16307
- Publication Date:
- 2014-10-10
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3765 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/chem.201404142 ↗
- Languages:
- English
- ISSNs:
- 0947-6539
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3168.860500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3971.xml