Back Cover: Facile Insertion of Carbon Dioxide into Cu2(μ‐H) Dinuclear Units Supported by Tetraphosphine Ligands (Chem. Asian J. 11/2014). Issue 11 (November 2014)

• Record Type: Journal Article
• Authors: Nakamae, Kanako; Kure, Bunsho; Nakajima, Takayuki; Ura, Yasuyuki; Tanase, Tomoaki
• Is Part Of: Chemistry, an Asian journal. Volume 9:Issue 11(2014:Nov.)
• Page Start: 3320
• Page End: 3320
• Publication Date: 2014-11
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.201490043
• Languages: English
• ISSNs: 1861-4728

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Hydrides</bold> Hydride‐bridged di‐ and tetracopper complexes supported by tetraphosphine ligands were prepared and found to be subject to facile insertion of CO₂, leading to formate‐bridged di‐ and tetracopper complexes, as reported by Tomoaki Tanase et al. in their Communication on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 3106 ff.</ext-link> (see the Back Cover). The experimental and DFT theoretical studies demonstrated that a novel CO₂ insertion into the Cu₂(μ‐H) unit occurred with the flexible dicopper platform, which should be highly important in relation to the insertion promoted on the surface of metallic copper materials.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgh2chc1wqt" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>