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ChemInform Abstract: Synthesis of Multi‐Substituted Vinylsilanes via Copper(I)‐Catalyzed Hydrosilylation Reactions of Allenes and Propiolate Derivatives with Silylboronates. Issue 48 (2nd December 2014)
Record Type:
Journal Article
Title:
ChemInform Abstract: Synthesis of Multi‐Substituted Vinylsilanes via Copper(I)‐Catalyzed Hydrosilylation Reactions of Allenes and Propiolate Derivatives with Silylboronates. Issue 48 (2nd December 2014)
Main Title:
ChemInform Abstract: Synthesis of Multi‐Substituted Vinylsilanes via Copper(I)‐Catalyzed Hydrosilylation Reactions of Allenes and Propiolate Derivatives with Silylboronates.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Multi‐substituted allenes with electron‐withdrawing groups, e.g. (I), (IV), and (VI) and propiolate derivatives (IX) react with silyl boronic acid ester (II) to afford silyl‐substituted butenoate derivatives (III), (V), and (VII)/(VIII) or β‐silyl‐substituted arylates (X), respectively.</p> </abstract>