ChemInform Abstract: Chiral Monodentate Phosphine Ligands for the Enantioselective α‐ and γ‐Arylation of Aldehydes. Issue 44 (4th November 2014) - Franzoni, Ivan
Abstract Chiral trialkyl monodentate phosphine ligands (I) elaborated on the binepine scaffold are synthesized and applied to the Pd‐catalyzed intramolecular asymmetric α‐arylation of aldehydes as well as the intermolecular asymmetric γ‐arylation of α, β‐unsaturated aldehydes.