Solvatochromic dipolarity micro‐sensor behaviour in binary solvent systems of the (water + ionic liquid) type: application of preferential solvation model and linear solvation energy relationships. (28th August 2014)

• Record Type: Journal Article
• Authors: Adam, Claudia G.; Bravo, M. Virginia; Mancini, Pedro M. E.; Fortunato, Graciela G.
• Is Part Of: Journal of physical organic chemistry. Volume 27:Number 11(2014:Nov.)
• Page Start: 841
• Page End: 849
• Publication Date: 2014-08-28
• Subjects: Chemistry, Physical organic -- Periodicals; 547.1
• DOI: 10.1002/poc.3346
• Languages: English
• ISSNs: 0894-3230

Abstract

<abstract abstract-type="main"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The type of specific <named-content content-type="reactionType" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">intermolecular</named-content> and interionic interactions that are established when an ionic liquid is dissolved in water was here analysed. The study of the solvatochromic response of dipolarity micro‐sensors based on Reichardt <italic>E</italic><sub>T</sub>(30) and Kamlet–Abboud–Taft solvent scales and the application of the <named-content content-type="chemicalTechnology" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">solvent exchange</named-content> model confirmed the formation of different intersolvent complexes in binary mixtures of (water + [C<sub>4</sub>mim] [BF<sub>4</sub>]/[Br]) type. These complexes provide H‐bond or electron pairs to the polar network, respectively. Moreover, for 4‐methoxybenzenesulfonyl chloride <named-content content-type="reactionType" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">hydrolysis</named-content> reaction in the (water + [C<sub>4</sub>mim] [BF<sub>4</sub>]) system, a higher inhibition (13 times) on the <italic>k</italic><sub>obs</sub> values was observed. Multiple linear <named-content content-type="chemicalTechnology" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">regression analysis</named-content> that allows confirming the solvent effect upon the reactive system is due to the hydrogen‐bond donor properties of intersolvent complex formed. Then, the correlation between two different solvent‐dependent processes proved to be successful. Copyright © 2014 John Wiley & Sons, Ltd.</p> </abstract>