Chelating Ruthenium Phenolate Complexes: Synthesis, General Catalytic Activity, and Applications in Olefin Metathesis Polymerization. Issue 43 (9th September 2014)

• Record Type: Journal Article
• Authors: Kozłowska, Anna; Dranka, Maciej; Zachara, Janusz; Pump, Eva; Slugovc, Christian; Skowerski, Krzysztof; Grela, Karol
• Is Part Of: Chemistry. Volume 20:Issue 43(2014)
• Page Start: 14120
• Page End: 14125
• Publication Date: 2014-09-09
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201403580
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Cyclic Ru‐phenolates were synthesized, and these compounds were used as olefin metathesis catalysts. Investigation of their catalytic activity pointed out that, after activation with chemical agents, these catalysts promote ring‐closing metathesis (RCM), enyne and cross‐metathesis (CM) reactions, including butenolysis, with good results. Importantly, these latent catalysts are soluble in neat dicyclopentadiene (DCPD) and show good applicability in ring‐opening metathesis polymeriyation (ROMP) of this monomer.</p> </abstract>