Fast Synthesis of Complex Enantiopure Heterocyclic Scaffolds by a Tandem Sequence of Simple Transformations on α‐Hydroxyaldehydes. Issue 28 (10th June 2013)

• Record Type: Journal Article
• Authors: Cannillo, Alexandre; Norsikian, Stéphanie; Retailleau, Pascal; Dau, Marie‐Elise Tran Huu; Iorga, Bogdan I.; Beau, Jean‐Marie
• Is Part Of: Chemistry. Volume 19:Issue 28(2013)
• Page Start: 9127
• Page End: 9131
• Publication Date: 2013-06-10
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201301712
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Two tandems are faster than one!</bold> Properly sequenced reactions initiated by the Petasis aminoalcohol synthesis from boronic acids, diallylamine, and α‐hydroxyaldehydes, including free aldoses, leads to rapid construction of complex enantiopure structures (see scheme).<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgh19108v8p" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>