Bioinspired Total Synthesis of Sespenine1. (24th June 2014)
- Record Type:
- Journal Article
- Title:
- Bioinspired Total Synthesis of Sespenine1. (24th June 2014)
- Main Title:
- Bioinspired Total Synthesis of Sespenine1
- Authors:
- Sun, Yu
Chen, Pengxi
Zhang, Deliang
Baunach, Martin
Hertweck, Christian
Li, Ang - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The first total synthesis of sespenine, a rare indole sesquiterpenoid from a mangrove endophyte, has been accomplished. A bioinspired aza‐Prins/Friedel–Crafts/retro Friedel–Crafts cascade reaction assembles the bridged tetrahydroquinoline core. Further investigations on the aza‐Prins cyclization imply that the C3 configuration of the hydroxyindolenine intermediate is crucial to the biosynthesis of sespenine and its congener xiamycin A.</p> </abstract>
- Is Part Of:
- Angewandte Chemie. Volume 126:Number 34(2014)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 126:Number 34(2014)
- Issue Display:
- Volume 126, Issue 34 (2014)
- Year:
- 2014
- Volume:
- 126
- Issue:
- 34
- Issue Sort Value:
- 2014-0126-0034-0000
- Page Start:
- 9158
- Page End:
- 9162
- Publication Date:
- 2014-06-24
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201404191 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 3311.xml