A New Reactivity Mode for the Diazo Group: Diastereoselective 1, 3‐Aminoalkylation Reaction of β‐Amino‐α‐Diazoesters To Give Triazolines1. (1st July 2014)
- Record Type:
- Journal Article
- Title:
- A New Reactivity Mode for the Diazo Group: Diastereoselective 1, 3‐Aminoalkylation Reaction of β‐Amino‐α‐Diazoesters To Give Triazolines1. (1st July 2014)
- Main Title:
- A New Reactivity Mode for the Diazo Group: Diastereoselective 1, 3‐Aminoalkylation Reaction of β‐Amino‐α‐Diazoesters To Give Triazolines1
- Authors:
- Kuznetsov, Alexey
Gulevich, Anton V.
Wink, Donald J.
Gevorgyan, Vladimir - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A novel mode of reactivity for the diazo group, the 1, 3‐addition of a nucleophile and an electrophile to the diazo group, has been realized in the intramolecular aminoalkylation of β‐amino‐α‐diazoesters to form tetrasubstituted 1, 2, 3‐triazolines. The reaction exhibited a broad scope, good functional group tolerance, and excellent diastereoselectivity. In addition, a new Au‐catalyzed intramolecular transannulation reaction of the obtained propargyl triazolines to give pyrroles has been discovered.</p> </abstract>
- Is Part Of:
- Angewandte Chemie. Volume 126:Number 34(2014)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 126:Number 34(2014)
- Issue Display:
- Volume 126, Issue 34 (2014)
- Year:
- 2014
- Volume:
- 126
- Issue:
- 34
- Issue Sort Value:
- 2014-0126-0034-0000
- Page Start:
- 9167
- Page End:
- 9171
- Publication Date:
- 2014-07-01
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201404352 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 3311.xml