Vortex Assisted Liquid–Liquid Microextraction Using Triton X‐114 for Ultratrace Cadmium Prior to Analysis. Issue 8 (26th November 2013)

• Record Type: Journal Article
• Authors: Khan, Sumaira; Yilmaz, Erkan; Kazi, Tasneem Gul; Soylak, Mustafa
• Is Part Of: Clean. Volume 42:Issue 8(2014:Aug.)
• Page Start: 1083
• Page End: 1088
• Publication Date: 2013-11-26
• Subjects: Water quality -- Periodicals; Water -- Pollution -- Periodicals; Pollution -- Periodicals; Bioremediation -- Periodicals; Sewage -- Periodicals; Water chemistry -- Periodicals; 333.7205
• DOI: 10.1002/clen.201300486
• Languages: English
• ISSNs: 1863-0650

Abstract

<abstract abstract-type="main"> <title> <x xml:space="preserve">Abstract</x> </title> <sec id="clen201300486-sec-0001" sec-type="section"> <p>A vortex‐assisted liquid–liquid microextraction method coupled to micro‐sample injection flame atomic absorption spectrometry for cadmium (Cd) determination in water samples, phenomena was established through phase separation of ionic surfactant in aqueous samples. The ionic liquid 1‐butyl‐3‐methylimidazolium hexafluorophosphate [C₄MIM][PF₆] was used as an extractant, while using Triton X‐114 as dispersing medium. The chelate of Cd with ammonium pyrrolidinedithiocarbamate (APDC) was extracted into the fine droplets. The main factors affecting the recovery values of Cd, such as [C₄MIM][PF₆], pH, TX‐114, concentration of APDC, centrifugation time and rate were investigated in detail. At optimum experimental values of significant variables, preconcentration factor of 20 was obtained. The validity of developed method was checked by Cd determination in certified reference material of water (TMDA‐54.4 fortified lake water) and the results were found good agreement with the certified values. The relative standard deviation was 4.2% for 100 µg Cd/L. The method was applied satisfactorily for the preconcentration of Cd in real samples.</p> </sec> </abstract>