Carbolithiation of Chloro‐Substituted Alkynes: A New Access to Vinyl Carbenoids. Issue 33 (17th July 2014)
- Record Type:
- Journal Article
- Title:
- Carbolithiation of Chloro‐Substituted Alkynes: A New Access to Vinyl Carbenoids. Issue 33 (17th July 2014)
- Main Title:
- Carbolithiation of Chloro‐Substituted Alkynes: A New Access to Vinyl Carbenoids
- Authors:
- Lhermet, Rudy
Ahmad, Maha
Fressigné, Catherine
Silvi, Bernard
Durandetti, Muriel
Maddaluno, Jacques - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The intramolecular carbolithiation of a series of chloro‐substituted alkynes leads to exocyclic alkylidene carbenoids of which both nucleophilic and electrophilic characters can be drove. A sole stereoselective 5‐<italic>exo‐dig</italic> addition takes place, probably because of a strong and persisting Li–Cl interaction arising before the transition state.</p> </abstract>
- Is Part Of:
- Chemistry. Volume 20:Issue 33(2014)
- Journal:
- Chemistry
- Issue:
- Volume 20:Issue 33(2014)
- Issue Display:
- Volume 20, Issue 33 (2014)
- Year:
- 2014
- Volume:
- 20
- Issue:
- 33
- Issue Sort Value:
- 2014-0020-0033-0000
- Page Start:
- 10249
- Page End:
- 10254
- Publication Date:
- 2014-07-17
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3765 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/chem.201403605 ↗
- Languages:
- English
- ISSNs:
- 0947-6539
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3168.860500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3406.xml