Photocatalytic Reduction of Carbon Dioxide over Self‐Assembled Carbon Nitride and Layered Double Hydroxide: The Role of Carbon Dioxide Enrichment. Issue 8 (2nd July 2014)

• Record Type: Journal Article
• Authors: Hong, Jindui; Zhang, Wei; Wang, Yabo; Zhou, Tianhua; Xu, Rong
• Is Part Of: ChemCatChem. Volume 6:Issue 8(2014:Aug.)
• Page Start: 2315
• Page End: 2321
• Publication Date: 2014-07-02
• Subjects: Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201402195
• Languages: English
• ISSNs: 1867-3880

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A self‐assembly of carbon nitride (C₃N₄) and layered double hydroxide (LDH) was constructed by electrostatic interaction. The pristine nitrate‐intercalated Mg‐Al‐LDH is turned to carbonate LDH through anion exchange during the photoreduction of CO₂ in aqueous solution. The carbonate anions enriched in the interlayer of LDH exhibit a remarkably high reduction efficiency to CH₄ in the presence of a C₃N₄ photoabsorber and Pd cocatalyst.</p> </abstract>