A Cyclization–Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)–Aminocarbene Complexes1. (7th July 2014)
- Record Type:
- Journal Article
- Title:
- A Cyclization–Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)–Aminocarbene Complexes1. (7th July 2014)
- Main Title:
- A Cyclization–Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)–Aminocarbene Complexes1
- Authors:
- Kolundžić, Filip
Murali, Annamalai
Pérez‐Galán, Patricia
Bauer, Jonathan O.
Strohmann, Carsten
Kumar, Kamal
Waldmann, Herbert - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A facile synthesis of chiral cyclic alkyl aminocarbene–gold(I) complexes from gold‐free 1, 7‐enyne substrates was developed. The novel cyclization–rearrangement reaction sequence is triggered by the addition of (Me<sub>2</sub>S)AuCl to different 1, 7‐enynes and leads to structurally unique carbene–gold(I) complexes in high yields. These novel complexes are catalytically active and inhibit the proliferation of different human cancer cell lines.</p> </abstract>
- Is Part Of:
- Angewandte Chemie. Volume 126:Number 31(2014)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 126:Number 31(2014)
- Issue Display:
- Volume 126, Issue 31 (2014)
- Year:
- 2014
- Volume:
- 126
- Issue:
- 31
- Issue Sort Value:
- 2014-0126-0031-0000
- Page Start:
- 8260
- Page End:
- 8264
- Publication Date:
- 2014-07-07
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201403651 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 4067.xml