Electrical Conductivity of SiOCN Ceramics by the Powder‐Solution‐Composite Technique. Issue 8 (12th May 2014)

• Record Type: Journal Article
• Authors: Nguyen, Van Lam; Zanella, Caterina; Bettotti, Paolo; Sorarù, Gian Domenico; Hay, R.
• Is Part Of: Journal of the American Ceramic Society. Volume 97:Issue 8(2014)
• Page Start: 2525
• Page End: 2530
• Publication Date: 2014-05-12
• Subjects: Ceramics -- Periodicals; 620.1405
• DOI: 10.1111/jace.12963
• Languages: English
• ISSNs: 0002-7820

Abstract

<abstract abstract-type="main" id="jace12963-abs-0001"> <title> <x xml:space="preserve">Abstract</x> </title> <p>SiOCN ceramics have been prepared by the polymer pyrolysis method. The preceramic polymers were synthesized from a polysiloxane cross‐linked with two different N‐containing compounds: a silazane or a ternary amine. The corresponding SiOCN ceramics were obtained by pyrolysis in nitrogen atmosphere at five different temperatures from 1000°C to 1400°C. The electrical conductivity of the powdered SiOCN ceramic samples was determined by the powder‐solution‐composite technique. The results show an increase in room temperature AC conductivity of three orders of magnitude, from ≈10⁻⁵ (S/cm) to ≈10⁻² (S/cm), with increasing pyrolysis temperature from 1000°C to 1400°C. Furthermore, the electrical conductivity of the amine‐derived SiOCN is three to five times higher than that of the silazane‐derived ceramic at each pyrolysis temperature. The combined structural study by Raman spectroscopy and chemical analysis suggests that the increase of electrical conductivity with the pyrolysis temperature is due to the <italic>sp</italic>³‐to‐<italic>sp</italic>² transition of the amorphous carbon phase. The higher conductivity of the amine‐derived SiOCN is also discussed considering features like the volume% of the free‐carbon phase and its possible N‐doping.</p> </abstract>