A one‐dimensional cobalt(II) coordination polymer based on 2, 4′‐oxydibenzoic acid: poly[[[diaquabis[2‐(4‐carboxyphenoxy)benzoato‐κO1]cobalt(II)]‐μ‐4, 4′‐bipyridine‐κ2N:N′] dihydrate]. Issue 7 (5th June 2014)

• Record Type: Journal Article
• Authors: Tang, Long; Fu, Feng; Wang, Ji‐Jiang; Liu, Qi‐Rui; Zhao, Hang‐Hang
• Is Part Of: Acta crystallographica. Volume 70:Issue 7(2014:Jul.)
• Page Start: 654
• Page End: 658
• Publication Date: 2014-06-05
• Subjects: Crystallography -- Periodicals; Crystals -- Periodicals; 548.3
• DOI: 10.1107/S2053229614012066
• Languages: English
• ISSNs: 2053-2296

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The reaction of CoSO₄ with 2, 4‐oxydibenzoic acid (H₂oba) and 4, 4′‐bipyridine (bipy) under hydrothermal condition yielded a new one‐dimensional cobalt(II) coordination polymer, {[Co(C₁₄H₉O₅)₂(C₁₀H₈N₂)(H₂O)₂]·2H₂O}_{<italic>n</italic>}, which was characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, magnetic properties and single‐crystal X‐ray diffraction. The Co^II ions are connected by bipy ligands into infinite one‐dimensional chains. The Hoba⁻ ligands extend out from the two sides of the one‐dimensional chain. O—H...O hydrogen bonding extends these chains into a two‐dimensional supramolecular architecture.</p> </abstract>