Poly(exTTF): A Novel Redox‐Active Polymer as Active Material for Li‐Organic Batteries. Issue 15 (23rd May 2014)

• Record Type: Journal Article
• Authors: Häupler, Bernhard; Burges, René; Friebe, Christian; Janoschka, Tobias; Schmidt, Daniel; Wild, Andreas; Schubert, Ulrich S.
• Is Part Of: Macromolecular rapid communications. Volume 35:Issue 15(2014:Aug.)
• Page Start: 1367
• Page End: 1371
• Publication Date: 2014-05-23
• Subjects: Macromolecules -- Periodicals; Polymers -- Periodicals; Chemistry -- Periodicals; 547.705
• DOI: 10.1002/marc.201400167
• Languages: English
• ISSNs: 1022-1336

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The first polymer bearing exTTF units intended for the use in electrical charge storage is presented. The polymer undergoes a redox reaction involving two electrons at −0.20 V vs Fc/Fc⁺ and is applied as active cathode material in a Li‐organic battery. The received coin cells feature a theoretical capacity of 132 mAh g⁻¹, a cell potential of 3.5 V, and a lifetime exceeding more than 250 cycles. <boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pghxn0nsmr" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>