Effect of the Branching Pattern of Hydrophobic Dendrons on the Core Structure of Linear‐Dendritic Copolymer Micelles. Issue 15 (16th June 2014)

• Record Type: Journal Article
• Authors: Kalva, Nagendra; Aswal, Vinod K.; Ambade, Ashootosh V.
• Is Part Of: Macromolecular chemistry and physics. Volume 215:Issue 15(2014:Aug.)
• Page Start: 1456
• Page End: 1465
• Publication Date: 2014-06-16
• Subjects: Polymers -- Periodicals; Polymerization -- Periodicals; Synthetic products -- Periodicals; Macromolecules -- Periodicals; 547.7
• DOI: 10.1002/macp.201400150
• Languages: English
• ISSNs: 1022-1352

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>Hydrophobic dendrons based on different branching patterns, viz. 3, 5‐di‐ and 3, 4, 5‐trisubstituted phenyl rings, consist of the same backbone but exhibit different sizes, shapes, and hydrophobic densities. These dendrons are attached to poly(ethylene glycol) and the core pro­perties of the copolymer micelles are investigated in tetrahydrofuran (THF)/water mixtures by neutron scattering. Two polymers with intermediate hydrophobicity are studied further with variations in the solvent composition and the temperature. The aggregation numbers for 3, 4, 5‐based dendron copolymers are lower, with more THF molecules of solvation compared with the 3, 5‐based dendron copolymer, the difference being greater at higher generations due to different molecular shapes. The micellar core size increases in small steps with dendron size so that dye encapsulation is tuned. <boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pghwm3hzc8" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>