A Physical Pulverization Strategy for Preparing a Highly Active Composite of CoOx and Crushed Graphite for Lithium–Oxygen Batteries. Issue 10 (24th June 2014)

• Record Type: Journal Article
• Authors: Ming, Jun; Kwak, Won‐Jin; Park, Jin‐Bum; Shin, Chang‐Dae; Lu, Jun; Curtiss, Larry; Amine, Khalil; Sun, Yang‐Kook
• Is Part Of: Chemphyschem. Volume 15:Issue 10(2014)
• Page Start: 2070
• Page End: 2076
• Publication Date: 2014-06-24
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.05
• DOI: 10.1002/cphc.201400054
• Languages: English
• ISSNs: 1439-4235

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A new physical pulverization strategy has been developed to prepare a highly active composite of CoO<sub><italic>x</italic></sub> and crushed graphite (CG) for the cathode in lithium–oxygen batteries. The effect of CoO<sub><italic>x</italic></sub> loading on the charge potential in the oxygen evolution reaction (Li<sub>2</sub>O<sub>2</sub>→2 Li<sup>+</sup>+O<sub>2</sub>+2e<sup>−</sup>) was investigated in coin‐cell tests. The CoO<sub><italic>x</italic></sub> (38.9 wt %)/CG composite showed a low charge potential of 3.92 V with a delivered capacity of 2 mAh cm<sup>−2</sup> under a current density of 0.2 mA cm<sup>−2</sup>. The charge potential was 4.10 and 4.15 V at a capacity of 5 and 10 mAh cm<sup>−2</sup>, respectively, with a current density of 0.5 mA cm<sup>−2</sup>. The stability of the electrolyte and discharge product on the gas‐diffusion layer after the cycling were preliminarily characterized by <sup>1</sup>H nuclear magnetic resonance spectroscopy, scanning electron microscopy, X‐ray photoelectron spectroscopy, and X‐ray diffraction. The high activity of the composite was further analyzed by electrochemical impedance spectroscopy, cyclic voltammetry, and potential‐step chronoamperometry. The results indicate that our near‐dry milling method is an effective and green approach to preparing a nanocomposite cathode with high surface area and porosity, while using less solvent. Its relative simplicity compared with the traditional solution method could facilitate its widespread application in catalysis, energy storage, and materials science.</p> </abstract>