<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A series of hemilabile 2‐(imidazol‐2‐yl)pyridine and 2‐(oxazol‐2‐yl)pyridine palladium ligands are synthesized, characterized, and their catalytic properties in high‐temperature Suzuki—Miyaura cross‐coupling reactions are investigated.</p> </abstract>