Catalytic Intermolecular Alkene Oxyamination with Nitrenes. Issue 29 (17th June 2014)
- Record Type:
- Journal Article
- Title:
- Catalytic Intermolecular Alkene Oxyamination with Nitrenes. Issue 29 (17th June 2014)
- Main Title:
- Catalytic Intermolecular Alkene Oxyamination with Nitrenes
- Authors:
- Dequirez, Geoffroy
Ciesielski, Jennifer
Retailleau, Pascal
Dauban, Philippe - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The Rh<sup>II</sup>‐catalyzed intermolecular addition of nitrenes to aromatic and aliphatic alkenes provides vicinal amino alcohols with yields of up to 95 % and complete regioselectivity. This 1, 2‐oxyamination reaction involves the formation of an aziridine intermediate that undergoes in situ ring opening. The latter is induced by the Rh‐bound nitrene that behaves as a Lewis acid.</p> </abstract>
- Is Part Of:
- Chemistry. Volume 20:Issue 29(2014)
- Journal:
- Chemistry
- Issue:
- Volume 20:Issue 29(2014)
- Issue Display:
- Volume 20, Issue 29 (2014)
- Year:
- 2014
- Volume:
- 20
- Issue:
- 29
- Issue Sort Value:
- 2014-0020-0029-0000
- Page Start:
- 8929
- Page End:
- 8933
- Publication Date:
- 2014-06-17
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3765 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/chem.201400301 ↗
- Languages:
- English
- ISSNs:
- 0947-6539
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3168.860500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3297.xml