A dmp‐type Microporous Cadmium(II)‐Isonicotinate: Synthesis, Structure and CO2 Adsorption Property. Issue 8 (13th March 2014)

• Record Type: Journal Article
• Authors: Zhang, Zhihua
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 640:Issue 8/9(2014)
• Page Start: 1737
• Page End: 1740
• Publication Date: 2014-03-13
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201400024
• Languages: English
• ISSNs: 0044-2313

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The 4‐connected <bold>dmp</bold>‐type cadmium(II)‐isonicotinate framework [Cd(isonic)₂(H₂O)]<italic>_n</italic><bold>·</bold><italic>n</italic>(DMA) (<bold>1</bold>) (isonic = isonicotinate, DMA = <italic>N</italic>, <italic>N</italic>′‐dimethylacetamide) was obtained by the solvothermal reactions of Cd(NO₃)₂ and isonicotinic acid (Hisonic). Compound <bold>1</bold> features a 3D porous framework with the opened channels occupied by the lattice DMA molecules. Thermal analysis reveals that such framework remains much stable after removal the free DMA molecules. CO₂ adsorption measurement shows that such framework exhibits notable CO₂ adsorption behavior.</p> </abstract>