H‐Phosphonate‐Mediated Amination of Quinoline N‐Oxides with Tertiary Amines: A Mild and Metal‐Free Synthesis of 2‐Dialkylaminoquinolines. Issue 9 (28th May 2014)

• Record Type: Journal Article
• Authors: Chen, Xiaolan; Li, Xu; Qu, Zhibo; Ke, Diandian; Qu, Lingbo; Duan, Likun; Mai, Wenpeng; Yuan, Jinwei; Chen, Jianyu; Zhao, Yufen
• Is Part Of: Advanced synthesis & catalysis. Volume 356:Issue 9(2014)
• Page Start: 1979
• Page End: 1985
• Publication Date: 2014-05-28
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201301065
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A synthetic strategy has been developed for the synthesis of 2‐dialkylaminoquinolines from easily available quinoline <italic>N</italic>‐oxides, tertiary amines, diisopropyl H‐phosphonate and carbon tetrachloride (CCl₄) in one pot under metal‐free conditions at room temperature.</p> <p> <boxed-text content-type="graphic" position="anchor" orientation="portrait"> <graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pghmfntpff" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> </boxed-text> </p> </abstract>