Charge‐Transfer Complex Crystal Based on Extended‐π‐Conjugated Acceptor and Sulfur‐Bridged Annulene: Charge‐Transfer Interaction and Remarkable High Ambipolar Transport Characteristics. (24th March 2014)

• Record Type: Journal Article
• Authors: Qin, Yunke; Zhang, Jing; Zheng, Xiaoyan; Geng, Hua; Zhao, Guangyao; Xu, Wei; Hu, Wenping; Shuai, Zhigang; Zhu, Daoben
• Is Part Of: Advanced materials. Volume 26:Number 24(2014)
• Page Start: 4093
• Page End: 4099
• Publication Date: 2014-03-24
• Subjects: Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201400056
• Languages: English
• ISSNs: 0935-9648

Abstract

<abstract abstract-type="graphical" xml:lang="en" id="adma201400056-abs-0001"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A single crystal</bold> of a novel mixed‐stack donor–acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π‐conjugated system and a sulfur‐bridged annulene displays the highest ambipolar transport behavior among donor–acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm² V⁻¹ s⁻¹, respectively. <boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pghmfnj5xv" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>