Cover Picture: An [Fe‐Fe]‐Hydrogenase Mimic Immobilized on MCM‐41 for the Photochemical Production of Hydrogen in Pure Water (Chin. J. Chem. 6/2014). Issue 6 (June 2014)

• Record Type: Journal Article
• Authors: Wang, Wen; Yu, Tianjun; Zeng, Yi; Chen, Jinping; Li, Yi
• Is Part Of: Chinese journal of chemistry. Volume 32:Issue 6(2014:Jun.)
• Page Start: 457
• Page End: 457
• Publication Date: 2014-06
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cjoc.201490012
• Languages: English
• ISSNs: 1001-604X

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>The cover picture shows</bold> a convenient approach for the application of water‐insoluble hydrogenase mimics in water. A hydrophobic hydrogenase mimic has been successfully applied to the photochemical production of hydrogen in pure water by immobilization of it into MCM‐41 with an iridium compound [Ir(ppy)₂bpy]Cl and triethylamine as the photosensitizer and the sacrificial electron donor, respectively. The immobilization stabilizes hydrogenase mimic, which endows the catalytic system good catalytic activity. The present study provides a general strategy for applying hydrophobic artificial catalysts in pure water by using mesoporous molecular. More details are discussed in the article by Li <italic>et al</italic>. on page 479–484.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pghmfzj6qz" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>