<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The first organocatalyzed, asymmetric oxa‐Michael addition of oximes to β‐CF<sub>3</sub>‐β‐substituted nitroalkenes (I) furnishing CF<sub>3</sub>‐containing oxime ethers (III) (13 examples) in high yields and enantioselectivities is described.</p> </abstract>