ChemInform Abstract: Boc‐Protected 1‐(3‐Oxocycloalkyl)ureas via a One‐Step Curtius Rearrangement: Mechanism and Scope. Issue 26 (1st July 2014)
- Record Type:
- Journal Article
- Title:
- ChemInform Abstract: Boc‐Protected 1‐(3‐Oxocycloalkyl)ureas via a One‐Step Curtius Rearrangement: Mechanism and Scope. Issue 26 (1st July 2014)
- Main Title:
- ChemInform Abstract: Boc‐Protected 1‐(3‐Oxocycloalkyl)ureas via a One‐Step Curtius Rearrangement: Mechanism and Scope.
- Authors:
- Sun, Xianyu
Rai, Rachita
Deschamps, Jeffrey R.
MacKerell, Alexander D. Jr.
Faden, Alan I.
Xue, Fengtian - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Treatment of carboxylic acids (I) with Et<sub>3</sub>N, DPPA, and tBuOH provides the title ureas as major products via Curtius rearrangement followed by an unexpected nucleophilic addition of the resulting tert‐butyl carbamate to an in situ generated isocyanate intermediate.</p> </abstract>
- Is Part Of:
- ChemInform. Volume 45:Issue 26(2014)
- Journal:
- ChemInform
- Issue:
- Volume 45:Issue 26(2014)
- Issue Display:
- Volume 45, Issue 26 (2014)
- Year:
- 2014
- Volume:
- 45
- Issue:
- 26
- Issue Sort Value:
- 2014-0045-0026-0000
- Page Start:
- no
- Page End:
- no
- Publication Date:
- 2014-07-01
- Subjects:
- Chemistry -- Abstracts -- Periodicals
540.5 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1522-2667 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/chin.201426061 ↗
- Languages:
- English
- ISSNs:
- 0931-7597
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3158.195000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3527.xml