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ChemInform Abstract: Application of a Mild Hydrothermal Approach Containing an in situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)‐Containing Fluorides Na4MU6F30 (M: Mn2+, Co2+, Ni2+, Cu2+, and Zn2+) Crystal Growth, Structures, and Magnetic Properties. Issue 26 (1st July 2014)
Record Type:
Journal Article
Title:
ChemInform Abstract: Application of a Mild Hydrothermal Approach Containing an in situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)‐Containing Fluorides Na4MU6F30 (M: Mn2+, Co2+, Ni2+, Cu2+, and Zn2+) Crystal Growth, Structures, and Magnetic Properties. Issue 26 (1st July 2014)
Main Title:
ChemInform Abstract: Application of a Mild Hydrothermal Approach Containing an in situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)‐Containing Fluorides Na4MU6F30 (M: Mn2+, Co2+, Ni2+, Cu2+, and Zn2+) Crystal Growth, Structures, and Magnetic Properties.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Single crystals of the title compounds are hydrothermally prepared from aqueous mixtures of UO<sub>2</sub>(OAc)<sub>2</sub>, NaF, HF, and MCl<sub>2</sub> (M: Mn, Co, Ni, Zn) or Cu(OAc)<sub>2</sub> (autoclave, 200 °C, 1 d, 20, 70, 60, 80, and about 100% yield for Mn‐, Co‐, Ni‐, Zn‐, and Cu‐containing materials, respectively).</p> </abstract>