Palladium‐Catalyzed Asymmetric Amination of Allenyl Phosphates: Enantioselective Synthesis of Allenes with an Additional Unsaturated Unit1. (2nd May 2014)
- Record Type:
- Journal Article
- Title:
- Palladium‐Catalyzed Asymmetric Amination of Allenyl Phosphates: Enantioselective Synthesis of Allenes with an Additional Unsaturated Unit1. (2nd May 2014)
- Main Title:
- Palladium‐Catalyzed Asymmetric Amination of Allenyl Phosphates: Enantioselective Synthesis of Allenes with an Additional Unsaturated Unit1
- Authors:
- Li, Qiankun
Fu, Chunling
Ma, Shengming - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A highly enantioselective Pd‐catalyzed amination of allenyl phosphates generating 2, 3‐allenyl amines with central chirality has been developed. Under the optimized conditions, chiral 2, 3‐allenyl amines with or without (an) additional CC double or triple bond(s) have been prepared at 0 °C with up to 90 % yield and 94 % <italic>ee</italic> by identifying (<italic>R</italic>)‐3, 4, 5‐(MeO)<sub>3</sub>‐MeOBIPHEP as the ligand.</p> </abstract>
- Is Part Of:
- Angewandte Chemie. Volume 126:Number 25(2014)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 126:Number 25(2014)
- Issue Display:
- Volume 126, Issue 25 (2014)
- Year:
- 2014
- Volume:
- 126
- Issue:
- 25
- Issue Sort Value:
- 2014-0126-0025-0000
- Page Start:
- 6629
- Page End:
- 6632
- Publication Date:
- 2014-05-02
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201402647 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 3159.xml