Thermal conductivity of diamond/Ag composites with chromium carbide coated diamonds for the building materials of high power modules. (July 2014)

• Record Type: Journal Article
• Authors: Zhao, C.; Gao, J. Z.
• Is Part Of: Materials science and technology. Volume 30:Number 7(2014:Jul.)
• Page Start: 800
• Page End: 805
• Publication Date: 2014-07
• Subjects: Materials science -- Periodicals; Microstructure -- Periodicals; Metallurgy -- Periodicals; 620.1105
• DOI: 10.1179/1743284713Y.0000000419
• Languages: English
• ISSNs: 0267-0836

Abstract

<abstract> <title> <x content-type="archive" xml:space="preserve">Abstract</x> </title> <p>This paper reports on a study of the preparation and characterisation of diamond/Ag composites for the building materials of high power modules. The Cr₇C₃ coated diamond particles are utilised to improve the interfacial bonding between the Ag and diamond and composites are prepared by hot pressing technique. The characteristics of Cr₇C₃ coating layers were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results show that the Cr₇C₃ coatings on the diamonds result in a strong interfacial bonding and a greatly enhanced thermal conductivity of the composites. A largely enhanced thermal conductivity of 768 W m⁻¹ K⁻¹ is obtained in Cr₇C₃ coated composites, which increases 168% relative to that of uncoated composites at 65% diamond volume fraction. The measured thermal conductivity agrees reasonably well with the predictions by a differential effective-medium (DEM) model.</p> </abstract>