3‐[(Diphenylphosphinothioyl)oxy]‐N‐methylpropan‐1‐aminium diphenylphosphanylthioate. Issue 3 (22nd February 2014)

• Record Type: Journal Article
• Authors: Karaman, Merve; İrişli, Sevil; Büyükgüngör, Orhan
• Is Part Of: Acta crystallographica. Volume 70:Issue 3(2014:Mar.)
• Page Start: 320
• Page End: 322
• Publication Date: 2014-02-22
• Subjects: Crystallography -- Periodicals; Crystals -- Periodicals; 548.3
• DOI: 10.1107/S2053229614002757
• Languages: English
• ISSNs: 2053-2296

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The title salt, C₁₆H₂₁NOPS⁺·C₁₂H₁₀OPS, was synthesized from the reaction between 3‐(methylamino)propan‐1‐ol and PPh₂(S)Cl in the presence of Et₃N. Its structure has been identified using spectroscopic methods and X‐ray analysis. Single crystals were obtained from ethanol by slow evaporation. In the asymmetric unit, a cation–anion pair is formed through an intermolecular N—H...O [N...O = 2.6974 (18) Å] hydrogen bond. The molecules are packed through N—H...O and N—H...S hydrogen bonds in the crystal and these hydrogen bonds are responsible for the high melting point. The P atoms of the anion and cation both have distorted tetrahedral environments.</p> </abstract>