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ChemInform Abstract: Catalytic Enantioselective Synthesis of α‐Substituted Secondary Allylic Alcohols from Terminal Alkynes and Aldehydes via Vinylaluminum Reagents. Issue 22 (3rd June 2014)
Record Type:
Journal Article
Title:
ChemInform Abstract: Catalytic Enantioselective Synthesis of α‐Substituted Secondary Allylic Alcohols from Terminal Alkynes and Aldehydes via Vinylaluminum Reagents. Issue 22 (3rd June 2014)
Main Title:
ChemInform Abstract: Catalytic Enantioselective Synthesis of α‐Substituted Secondary Allylic Alcohols from Terminal Alkynes and Aldehydes via Vinylaluminum Reagents.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The use of Me<sub>2</sub>AlH is essential in the Ni‐catalyzed hydroalumination step to generate reactivity‐tuned vinylaluminum reagents not able to reduce the aldehyde starting material.</p> </abstract>