<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A facile synthesis of chiral 2‐amino‐4H‐chromene derivatives with excellent enantioselectivity (up to 99% e.e.) via a binaphthyl‐modified squaramide‐catalyzed Michael addition of cyclohexanedione to benzylidenemalonitriles is developed.</p> </abstract>