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ChemInform Abstract: Bio‐Inspired Formal Synthesis of Hirsutellones A—C Featuring an Electrophilic Cyclization Triggered by Remote Lewis Acid‐Activation. Issue 19 (13th May 2014)
Record Type:
Journal Article
Title:
ChemInform Abstract: Bio‐Inspired Formal Synthesis of Hirsutellones A—C Featuring an Electrophilic Cyclization Triggered by Remote Lewis Acid‐Activation. Issue 19 (13th May 2014)
Main Title:
ChemInform Abstract: Bio‐Inspired Formal Synthesis of Hirsutellones A—C Featuring an Electrophilic Cyclization Triggered by Remote Lewis Acid‐Activation.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A bio‐inspired strategy is used to complete the formal synthesis of the antitubercular hirsutellone B (I) and congeners A (II) and C (III), through construction of its decahydrofluorene core from a linear polyene strand activated at both ends by a silyl enol ether and an allyl acetate (not shown).</p> </abstract>