Ionic Liquid–Sulfolane Composite Electrolytes for High‐Performance and Stable Dye‐Sensitized Solar Cells. Issue 6 (11th November 2013)

• Record Type: Journal Article
• Authors: Marszalek, Magdalena; Arendse, Francine Duriaux; Decoppet, Jean‐David; Babkair, Saeed Salem; Ansari, Azhar Ahmad; Habib, Sami S.; Wang, Mingkui; Zakeeruddin, Shaik M.; Grätzel, Michael
• Is Part Of: Advanced energy materials. Volume 4:Issue 6(2014:Jun.)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2013-11-11
• Subjects: Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201301235
• Languages: English
• ISSNs: 1614-6832

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>Ionic liquid electrolytes are prepared using sulfolane as a plasticizer for eutectic melts to realize highly stable and efficiently performing dye‐sensitized solar cells (DSCs) in hot climate conditions. Variations in the viscosity of the formulations with sulfolane content are measured and performance in DSCs is investigated using the ruthenium dye C106 as a sensitizer. A power conversion efficiency (PCE) of 8.2% is achieved under standard reporting conditions. Apart from lowering the viscosity, the addition of sulfolane induces a negative shift of the TiO₂ conduction band edge. Strikingly the device performance increases to 8.4% at 50 °C due to higher short circuit photocurrent and fill factor, over‐compensating the loss in open circuit voltage with increasing temperature. The PCE increases also upon decreasing the light intensity of the solar simulator, reaching up to 9% at 50 mW cm⁻². Devices based on these new electrolyte formulations show excellent stability during light soaking for 2320 h under full sunlight at 60 °C and also during a 1065 h long heat stress at 80 °C in the dark. A detailed investigation provides important information about the factors affecting the principal photovoltaic parameters during the aging process and the first results from a series of outdoor measurements are reported.</p> </abstract>