Compositionally Modulated Magnetic Epitaxial Spinel/Perovskite Nanocomposite Thin Films. (11th December 2013)

• Record Type: Journal Article
• Authors: Kim, Dong Hun; Aimon, Nicolas M.; Sun, Xueyin; Ross, Caroline A.
• Is Part Of: Advanced functional materials. Volume 24:Number 16(2014)
• Page Start: 2334
• Page End: 2342
• Publication Date: 2013-12-11
• Subjects: Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201302844
• Languages: English
• ISSNs: 1616-301X

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>There is great interest in self‐assembled oxide vertical nanocomposite films consisting of epitaxial spinel pillars in a single crystal perovskite matrix, due to their tunable electronic, magnetic, and multiferroic properties. Varying the composition or geometry of the pillars in the out‐of‐plane direction has not been previously reported but can provide new routes to tailoring their properties in three dimensions. In this work, ferrimagnetic epitaxial CoFe<sub>2</sub>O<sub>4</sub>, MgFe<sub>2</sub>O<sub>4</sub>, or NiFe<sub>2</sub>O<sub>4</sub> spinel nanopillars with an out‐of‐plane modulation in their composition and shape are grown in a BiFeO<sub>3</sub> matrix on a (001) SrTiO<sub>3</sub> substrate using pulsed laser deposition. Changing the pillar composition during growth produces a homogeneous pillar composition due to cation interdiffusion, but this can be suppressed using a sufficiently thick blocking layer of BiFeO<sub>3</sub> to produce bi‐pillar films containing for example a layer of magnetically hard CoFe<sub>2</sub>O<sub>4</sub> pillars and a layer of magnetically soft MgFe<sub>2</sub>O<sub>4</sub> pillars, which form in different locations. A thinner blocking layer enables contact between the top of the CoFe<sub>2</sub>O<sub>4</sub> and the bottom of the MgFe<sub>2</sub>O<sub>4</sub> which leads to correlated growth of the MgFe<sub>2</sub>O<sub>4</sub> pillars directly above the CoFe<sub>2</sub>O<sub>4</sub> pillars and provides a path for interdiffusion. The magnetic hysteresis of the nanocomposites is related to the pillar structure.</p> </abstract>